Synthesis of the chiral tripyridyldiamine ligand Bn-CDPy3 and characterization of its Co(III) complex [Co(Bn-CDPy3)Cl]Cl2.
نویسندگان
چکیده
Synthesis of the tripyridyldiamine Bn-CDPy3, a chiral pentadentate ligand, and characterization of its low-spin Co(III) complex [Co(Bn-CDPy3)Cl]Cl2 by X-ray crystallography, 1H NMR, 13C NMR, IR and UV-vis spectroscopy as well as molar conductivity and mass spectrometry, is described.
منابع مشابه
Synthesis, characterization, and theoretical studies of metal complexes derived from the chiral tripyridyldiamine ligand Bn-CDPy3.
Synthesis and characterization of metal complexes of the chiral tripyridyldiamine ligand Bn-CDPy3 (1), derived from trans-1,2-diaminocyclohexane, are described, along with theoretical studies that support the experimental data. These studies confirm that a single coordination geometry, out of five possible, is favored for octahedral complexes of the type [M(Bn-CDPy3)Cl], where M equals Co(III),...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 36 شماره
صفحات -
تاریخ انتشار 2008